She subsequently released her third album, My Other Self on 7 September 2007.
During this period of time, she also released her 4th album, Not Yet a Woman, which features the insert song "太煩惱" (Too Much Trouble) and the theme song "帶我走" (Take Me Away) that were featured Miss No Good.
In 2009, Yang starred in To Get Her with Jiro Wang of Fahrenheit and George Hu.
Devil Beside You was well received, allowing Yang's career to take off.
The same year, she released her debut album, My Intuition, featuring her hit song "曖昧" (Intuition) as the theme song of Devil Beside You and 理想情人" (Ideal Lover).
Next she filmed The Child's Eye in Thailand, a horror flick directed by the Pang Brothers with Elanne Kong, and also Taiwanese drama Hi My Sweetheart with Show Luo, which first aired on CTS and GTV on 1 November 2009.
Yang released her first collection album, Whimsical World Collection on 23 April 2010.It consists of 3 CDs and a DVD with 3 new tracks, 35 previously released tracks and 15 music videos from her five studio albums.Followed by her first concert, held on 24 April 2010 at Taipei Arena, with Jerry Yan as her special guest On 22 October 2010, she was awarded Best Actress at the 45th Golden Bell Awards, for her role as Chen Bao Zhu (陳寶茱) in Hi My Sweetheart.In 2006, she released her follow-up album, Meeting Love, which also sold very well at around 1.4 million.On 8 January 2007, Yang recorded her last "Guess Guess Guess" show due to her busy schedule and focus upon her music/acting career.Although Rainie has been embroiled in several scandals and rumours over the years, the 29-year-old has always been honest about her relationships, and once admitted that popular TV host and singer Xiao Gui used to be her first love.